A copper(i) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

Tomoki Nishiyama, Hirotaka Kitoh-Nishioka, Senku Tanaka, Masahiko Maekawa, Takayoshi Kuroda-Sowa, Masaki Yoshida, Masako Kato, Takashi Okubo
January 2024
Cite DOI URL

Abstract

A coordination polymer, [Cu(SCN)(iqi)]n (iqi = isoquinoline), containing copper(i) thiocyanate and a nitrogen-containing π-conjugated ligand, iqi, has been synthesized and its physical properties were evaluated. This coordination polymer has a two-dimensional (2D) sheet structure consisting of copper(i) thiocyanate and shows photoluminescence derived from 3MLCT and photoconductive properties.

Type
2
Publication
Dalton Trans.
Hirotaka Kitoh-Nishioka
Hirotaka Kitoh-Nishioka
Proffesor(Asociate)

My main research theme is to understand the quantum mechanical mechanisms of photoelectric energy conversion in solar cells and photosynthesis through computer simulations.